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- W45595874 abstract "Abstract The article describes the thermal behaviour of Cu(II) complexes formed with ligands R1R2NCXCOOK (R1R2=H or CH3, X=O or S). The oxamates form 2/1 complexes Cu(R1R2NCOCOO)2·xH2O and deprotonated ionic complexes K2Cu[R2NCOCOO]2·yH2O. These compounds form polymers by thermal decomposition and deprotonation of the primary or secondary amide function. The ligands break at the C–C bond by forming mainly CO2 and oxamides (R1R2NCOCONR1R2), by recombination of the amide functional groups. The thiooxamates also form 2/1 complexes and decompose without forming any other stable compound." @default.
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- W45595874 date "1998-03-01" @default.
- W45595874 modified "2023-09-24" @default.
- W45595874 title "Thermal analysis of oxamates, thiooxamates and their complexes" @default.
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- W45595874 doi "https://doi.org/10.1016/s0040-6031(97)00450-4" @default.
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