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- W45677105 abstract "A series of CuO modified zeolites samples were prepared by use of the methods like calcination, microwave radiation and impregnation. Their catalytic behaviors in degradation of N-nitrosopyrrolidine (NPYR) were investigated by temperature programmed surface reaction (TPSR), pulse reaction, and the technique of XRD, TPD, XPS and TG-MS etc. The degradation temperature of NPYR on CuO/NaY(imp) was lowered and the maximum concentration of the products NOx emerged earlier than that on NaY zeolite in the TPSR experiment. Cu 2+ or Cu + were the active species, and the Cu components in the sample migrated to internal pore during the degradation of NPYR. In the degradation of NPYR the products of NO, N 2 O, 2-methyl pyrrolidine, pyrrolidine, 2,3-dimethyl-2-nitro-butylamine, and N -methyl-butylamine were monitored by MS. The efficiency of copper modified zeolite NaY for elimination of nitrosamines and PAH's in smoldering smoke of cigarette was examined, and incorporation of copper was indeed beneficial for removing the carcinogens in smoke." @default.
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- W45677105 date "2004-01-01" @default.
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- W45677105 title "Copper oxide modified NaY zeolite: Efficient catalysts for degrading N-nitrosopyrrolidine" @default.
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- W45677105 doi "https://doi.org/10.1016/s0167-2991(04)80520-2" @default.
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