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- W45681936 abstract "Publisher Summary The chapter reviews the thermodynamics of crystallization pressure. Crystallization pressure results when a growing crystal encounters a pore wall. The maximum stress that a crystal of salt can exert is related to the supersaturation of the pore liquid, but the lower limits are set by the interfacial energies of the crystal and the wall, the pore size, and the pressure in the liquid. In nonequilibrium thermodynamics of crystallization pressure, evaporation drives the liquid/vapor meniscus into the gap between a crystal and the pore wall. If a large pore is nearly filled with salt, then the gap between the crystal and the wall effectively constitutes a small pore, and large stresses can develop in that region. Therefore, even stone that has no small pores can experience high crystallization pressure, when the pores are filled with salt. The chapter discusses the equations for disjoining pressure, supersaturation, and crystallization pressure." @default.
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- W45681936 date "2000-01-01" @default.
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- W45681936 title "Stress from crystallization of salt in pores" @default.
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- W45681936 doi "https://doi.org/10.1016/b978-044450517-0/50100-8" @default.
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