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- W45689939 abstract "BS>Beryllium chloride undergoes solvolysis in ethyl acetatedinitrogen tetroxide mixtures to give pale-straw crystals of the addition compound Be(NO/sub 3/)/sub 2/, 2N/sub 2/O/sub 4/. When heated in a vacuum, this decomposes in two stages. Dinitrogen tetroxide is evolved rapidly above 500, leaving anhydrous beryllium nitrate, Be(NO/sub 3/)/sub 2/, as a white powder which has no detectable volatility. At about 125 deg , sudden decomposition occurs to give dinitrogen tetroxide and a volatile beryllium compound which separates from the gas phase as colorless crystals. Analyses correspond with the formula Be/sub 4/ O(NO/sub 3/)/sub 6/(found: Be, 8.5, N, 19.5. Calculated for Be/sub 4/O(NO/sub 3/ )/sub 6/: Be 8.5; N 19 %). The structure, which the basic nitrate is believed to possess, is given. The basic nitrate is analogous with basic beryllium acetate and properties of the two compounds are compared. (P.C.H.)" @default.
- W45689939 created "2016-06-24" @default.
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- W45689939 date "1961-07-01" @default.
- W45689939 modified "2023-09-23" @default.
- W45689939 title "BASIC BERYLLIUM NITRATE" @default.
- W45689939 hasPublicationYear "1961" @default.
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