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- W45705936 abstract "Mississippian and Devonian oil shale samples from the Means Project were pyrolysed by Modified Fischer Assay and Material Balance Modified Fischer Assay. Organic elemental conversion characteristics were determined after analysis of the assay feed, products and residues. Organic matter was concentrated from the fresh shale and the assay residue, its elemental composition determined and compared with the product oil and gas compositions. Organic hydrogen balances around pyrolysis processes were constructed using the elemental composition of the concentrated organic matter and the oil and gas compositions. The study confirmed that organic carbon levels on fresh and spent shales are linearly related to oil shale grade and that organic carbon conversion to products is non-linear and appears to approach an asymptotic limit. The correlations developed are compared with similar data for other oil shales. Process material, elemental and fuel balances can be derived from the correlations. The oil shales examined contain Type II kerogens. Organic carbon conversions to oil ranged from 31 to 39%, averaging 35%. An average of 90% of the organic hydrogen in the fresh shale could be accounted for in the oil, spent shale and gas products. Simplified kerogen decomposition equations were developed for each sample based on carbonmore » accountability averaging 99%.« less" @default.
- W45705936 created "2016-06-24" @default.
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- W45705936 date "1985-02-01" @default.
- W45705936 modified "2023-09-27" @default.
- W45705936 title "Kerogen and pyrolysis studies of Mississippian and Devonian Oil Shale from the Means Project, East-Central Kentucky" @default.
- W45705936 hasPublicationYear "1985" @default.
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