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- W45852775 abstract "The design and construction of a special cell to measure the vapor pressure of air-sensitive compounds is described. Cyclohexane was used to calibrate this device prior to the measurement of vapor pressure as a function of temperature for several third row transition metal complexes. HIr(PF{sub 3}){sub 4} was found to be stable for hours at 86{degree}C, developing a vapor pressure of 711 torr. (HFACAC) AuMe{sub 2} showed a pressure of 140 torr at 58{degree}C while Pt(PF{sub 3}){sub 4} displayed 240 torr at 55{degree}C. The vapor pressure curves and linear equations are given for all three compounds. Attempts to achieve higher pressures by heating of latter two compounds were unsuccessful; thermal decomposition was evident above 65{degree}C. Addition of excess trifluorophosphine to the platinum complex to slow the decomposition was largely ineffective. 8 refs., 6 figs." @default.
- W45852775 created "2016-06-24" @default.
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- W45852775 date "1989-09-18" @default.
- W45852775 modified "2023-09-27" @default.
- W45852775 title "Vapor pressure measurements of volatile transition-metal complexes" @default.
- W45852775 hasPublicationYear "1989" @default.
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