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• W45956303 abstract "Monoclinic crystals of metallic (SN) x may be synthesized by the solid state polymerization of S 2 N 2 at room temperature. The monoclinic form may be converted to an orthorhombic form by mechanical shearing. When monoclinic (SN) x is heated at 145° it depolymerizes to a gaseous, very reactive isomer of S 4 N 4 which re-polymerizes on room temperature glass or plastic substrates to give golden, metallic (SN) x films. Crystals of (SN) x have a large conductivity at room temperature which shows the temperature dependence characteristic of metals, increasing rapidly with decreasing temperature. When (SN) x is treated with bromine vapor at room temperature it is converted to shiny black crystals of (SNBr 0.55 ) x which lose bromine on pumping at room temperature to give compositions in the range (SNBr y ) x (y ˜ 0.3−0.4). Simultaneous heating and pumping yields copper-colored crystals of (SNBr 0.25 ) x . All the brominated species are apparently metals having a higher conductivity than (SN) x Conductivity and optical reflectance measurements strongly suggest that the brominated polymers are more anisotropic in their metallic properties than (SN) x ." @default.
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• W45956303 date "1978-01-01" @default.
• W45956303 modified "2023-09-26" @default.
• W45956303 title "POLYMERIC SULFUR NITRIDE, (SN)X, AND ITS HALOGEN DERIVATIVES" @default.
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• W45956303 doi "https://doi.org/10.1016/b978-0-12-160850-7.50034-4" @default.
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