FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W45978069> ?p ?o ?g. }

• W45978069 abstract "This thesis considers a nanotechnology approach based on the production of metals pre-treatments and organic coatings (a complete protection system at all) designed from the nanoscale. The final aim is to develop protection systems with improved corrosion protection properties and a low environmental impact. In particular, multifunctional silane hybrid molecules were used to design sol-gel pre-treatments for metals and to modify the inner structure ofUV curable waterborne organic coatings. In the first part of this thesis thin (hundreds of nanometers) sol-gel films consisting of an experimental mixture of hybrid silicon alkoxides molecules were applied onto aluminium and hot dipgalvanized (HDG) steel for the development of effective and environmentally friendly corrosion protection systems A chemical and electrochemical characterization of the sol-gel films highlighted their good corrosion protection properties both for aluminium and HDG steel. To test the effectiveness of the sol-gel coatings as coupling agent between metallic substrates and organic coatings (paints) both a powder coating paint and a cataphoretic coating paintwere applied on the silane pre-treated substrates. The electrochemical measurements and the accelerated tests carried out on these protection systems proved the capability of these sol-gel conversion coatings to improve the corrosion protection properties of the traditional protective cycles. The performance of the silane pre-treatments was also compared to commonly used surface conversion coatings for metals. The result of this comparison evidenced that the corrosion protection properties ensured by the sol-gel conversion treatment is comparable or higher than most of the commonly used pretreatments.A study about the incorporation of inorganic nanoparticles into these sol-gel films gave evidences of an improved corrosion resistance due to the addition of certain amount of montmorillonite nanoparticles in the sol-gel matrix. Thesame hybrid silicon alkoxide molecules used to perform the pre-treatments were used modify the inner structure of UV curable waterborne coatings in order to improve the corrosion protection properties maintaining the environmental compatibility of the protecting system. The design, application and characterisation of urethane, acrylic and epoxy waterborne UV curing coatings modified with the hybrid silicon molecules in order to obtain nanostructured waterborne films with improved corrosion resistance and thermomechanical properties were studied. The characterization proved the great potential of the silicon alkoxide molecules as a tool to modify the properties of the organic matrix of the paint: silicon alkoxides can promote the self assembly of inorganic nanoparticles into the matrix or can act as an effective coupling agent between inorganic nanoparticles and the polymeric matrix. Silicon alkoxide molecules were proved to be an efficient tool to design a protection system from the nanoscale leading to the prospective of an accurate control of the overall properties of the macroscopic systems." @default.
• W45978069 created "2016-06-24" @default.
• W45978069 creator A5063903022 @default.
• W45978069 date "2009-12-21" @default.
• W45978069 modified "2023-09-26" @default.
• W45978069 title "Environmentally friendly hybrid coatings for corrosion protection: silane based pre-treatments and nanostructured waterborne coatings" @default.
• W45978069 cites W1495876001 @default.
• W45978069 cites W1497330572 @default.
• W45978069 cites W1528457058 @default.
• W45978069 cites W1563184506 @default.
• W45978069 cites W1564125504 @default.
• W45978069 cites W2114831450 @default.
• W45978069 cites W586102426 @default.
• W45978069 hasPublicationYear "2009" @default.
• W45978069 type Work @default.
• W45978069 sameAs 45978069 @default.
• W45978069 citedByCount "1" @default.
• W45978069 crossrefType "dissertation" @default.
• W45978069 hasAuthorship W45978069A5063903022 @default.
• W45978069 hasConcept C127413603 @default.
• W45978069 hasConcept C147280077 @default.
• W45978069 hasConcept C147789679 @default.
• W45978069 hasConcept C159985019 @default.
• W45978069 hasConcept C171250308 @default.
• W45978069 hasConcept C171534860 @default.
• W45978069 hasConcept C17525397 @default.
• W45978069 hasConcept C185592680 @default.
• W45978069 hasConcept C18903297 @default.
• W45978069 hasConcept C191897082 @default.
• W45978069 hasConcept C192562407 @default.
• W45978069 hasConcept C20625102 @default.
• W45978069 hasConcept C27019838 @default.
• W45978069 hasConcept C2778024649 @default.
• W45978069 hasConcept C2779227376 @default.
• W45978069 hasConcept C2781448156 @default.
• W45978069 hasConcept C38398224 @default.
• W45978069 hasConcept C42360764 @default.
• W45978069 hasConcept C513153333 @default.
• W45978069 hasConcept C52859227 @default.
• W45978069 hasConcept C77066764 @default.
• W45978069 hasConcept C86803240 @default.
• W45978069 hasConcept C8846229 @default.
• W45978069 hasConceptScore W45978069C127413603 @default.
• W45978069 hasConceptScore W45978069C147280077 @default.
• W45978069 hasConceptScore W45978069C147789679 @default.
• W45978069 hasConceptScore W45978069C159985019 @default.
• W45978069 hasConceptScore W45978069C171250308 @default.
• W45978069 hasConceptScore W45978069C171534860 @default.
• W45978069 hasConceptScore W45978069C17525397 @default.
• W45978069 hasConceptScore W45978069C185592680 @default.
• W45978069 hasConceptScore W45978069C18903297 @default.
• W45978069 hasConceptScore W45978069C191897082 @default.
• W45978069 hasConceptScore W45978069C192562407 @default.
• W45978069 hasConceptScore W45978069C20625102 @default.
• W45978069 hasConceptScore W45978069C27019838 @default.
• W45978069 hasConceptScore W45978069C2778024649 @default.
• W45978069 hasConceptScore W45978069C2779227376 @default.
• W45978069 hasConceptScore W45978069C2781448156 @default.
• W45978069 hasConceptScore W45978069C38398224 @default.
• W45978069 hasConceptScore W45978069C42360764 @default.
• W45978069 hasConceptScore W45978069C513153333 @default.
• W45978069 hasConceptScore W45978069C52859227 @default.
• W45978069 hasConceptScore W45978069C77066764 @default.
• W45978069 hasConceptScore W45978069C86803240 @default.
• W45978069 hasConceptScore W45978069C8846229 @default.
• W45978069 hasLocation W459780691 @default.
• W45978069 hasOpenAccess W45978069 @default.
• W45978069 hasPrimaryLocation W459780691 @default.
• W45978069 hasRelatedWork W1510782100 @default.
• W45978069 hasRelatedWork W1973927459 @default.
• W45978069 hasRelatedWork W1992311952 @default.
• W45978069 hasRelatedWork W1994653296 @default.
• W45978069 hasRelatedWork W2020204810 @default.
• W45978069 hasRelatedWork W2034094242 @default.
• W45978069 hasRelatedWork W2036641972 @default.
• W45978069 hasRelatedWork W2042494259 @default.
• W45978069 hasRelatedWork W2067907005 @default.
• W45978069 hasRelatedWork W2072104927 @default.
• W45978069 hasRelatedWork W2092098019 @default.
• W45978069 hasRelatedWork W2258937812 @default.
• W45978069 hasRelatedWork W2293305203 @default.
• W45978069 hasRelatedWork W2347244529 @default.
• W45978069 hasRelatedWork W2348454655 @default.
• W45978069 hasRelatedWork W2402550665 @default.
• W45978069 hasRelatedWork W2910194514 @default.
• W45978069 hasRelatedWork W2990587505 @default.
• W45978069 hasRelatedWork W3134135512 @default.
• W45978069 hasRelatedWork W68682646 @default.
• W45978069 isParatext "false" @default.
• W45978069 isRetracted "false" @default.
• W45978069 magId "45978069" @default.
• W45978069 workType "dissertation" @default.