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- W46074085 abstract "Publisher SummaryThis chapter presents the empirical data derived from conventional kinetics experiments, that is, rate constants, activation energies, and preexponential factors are considered. Comparison with theory is carried out at two different levels. It discusses values of the kinetic parameters for a particular kind of reaction. Major errors in rate constant determinations are very rarely caused by flaws in the observational technique at present. They arise because nearly always observations are made on only a limited number of the species participating in the chemical changes that are occurring in the reaction mixture. Frequently, the concentration of only a single species is monitored directly. This will not lead to errors as long as the concentration of the observed species is only altered by the single reaction whose kinetics are supposedly being studied or if a more complicated reaction mechanism correctly identifies all the processes contributing to its removal." @default.
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- W46074085 date "1980-01-01" @default.
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- W46074085 title "Thermal rate data" @default.
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- W46074085 doi "https://doi.org/10.1016/b978-0-408-70790-9.50010-4" @default.
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