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- W46090595 abstract "Abstract The influence of peripheral substituents and axial ligands nature in a series of highly soluble in benzene cobaltous phthalocyanine derivatives on velocities and mechanisms of cumene hydroperoxide catalytic decomposition, of cyclohexane oxidation and catalyst destruction in the presence of cumene hydroperoxide was studied. The structural factors increasing the stability of catalyst with comparatively little decrease of its activity were determined. The interesting phenomenon of catalyst stabilization by cyclohexyl radicals due to their axial coordination was detected. The routes of efficient catalysts design were proposed." @default.
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- W46090595 date "1991-01-01" @default.
- W46090595 modified "2023-09-26" @default.
- W46090595 title "Phthalocyanine Derivatives as Catalysts for Soft Peroxidative Oxidation" @default.
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- W46090595 doi "https://doi.org/10.1016/s0167-2991(08)62865-7" @default.
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