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- W46188533 abstract "A new method, proposed for the preparation of very small (d = 20-70 a) monodisperse particles of Ni 2 B, Co 2 B and Ni-Co-B, is examined from a mechanistic point of view. These catalysts are synthesized by reduction with NaBH 4 of Ni 2+ and Co 2+ ions solubilized in a reversed micellar system composed of CTAB (cetyltrimethylammonium bromide), 1-hexanol and water. This work points out the role of micelles in obtaining colloidal catalysts as well as the essential parameters which control the size of particles formed in this system. The catalytic properties of the bimetallic particles are tested for the room temperature liquid phase hydrogenation of crotonaldehyde." @default.
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- W46188533 date "1987-01-01" @default.
- W46188533 modified "2023-09-27" @default.
- W46188533 title "On the Mechanism of Formation of Colloidal Monodisperse Metal Boride Particles from Reversed Micelles Composed of Ctab-1-Hexanol — Water" @default.
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- W46188533 doi "https://doi.org/10.1016/s0167-2991(08)65432-4" @default.
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