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- W49328359 abstract "The interest of electrochemists in the process of electrochemical oxidation of sulfur dioxide was aroused many years ago in connection with the well-known and rather old idea that the process of catalytic oxidation of SO/sub 2/ could possibly be replaced by an electrochemical process. This is attractive in terms of energy saving and also in terms of overall ecology. The difficulties in finding an acceptable engineering solution are due largely to the lack of any highly active electrocatalysts that are not in short supply. The present work has been devoted to the development and investigation of model electrodes based on carbonaceous materials promoted by metal phthalocyanines. These macrocyclic complexes were selected as objects of investigation because of their high activity in a great number of catalytic and electrocatalytic reactions, and also their high chemical and thermal stability. The presence of a well-developed conjugated system of ..pi..-electrons that has buffer properties is responsible for the fact that metal phthalocyanines manifest both donor and acceptor properties." @default.
- W49328359 created "2016-06-24" @default.
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- W49328359 date "1983-07-20" @default.
- W49328359 modified "2023-09-26" @default.
- W49328359 title "Electrooxidation of sulfur dioxide on phthalocyanines" @default.
- W49328359 hasPublicationYear "1983" @default.
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