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- W49590900 abstract "The asymmetrically modified nickel catalyst (MNi) is the simplest catalyst for the preparation of optically active compounds. MNi can be prepared easily by soaking activated nickel powder in an aqueous solution of an optically active compound. The unique functions of MNi are those associated with cooperation between an activated metal surface of macromolecular dimensions and the optically active compound implanted on the metal surface in a dispersed mono- molecular form. The metal surface functions as a generator of activated hydrogen for hydrogenation while the optically active compound acts as a stereochemical regulator of the reactant molecule. In this respect, studies on MNi catalysts have contributed not only to the development of a significant catalyst for the syntheses of optically active compounds, but also to an understanding of various characteristic phenomena taking place on the surface of nickel catalysts." @default.
- W49590900 created "2016-06-24" @default.
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- W49590900 date "1986-01-01" @default.
- W49590900 modified "2023-10-11" @default.
- W49590900 title "Asymmetrically Modified Nickel Catalysts" @default.
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- W49590900 doi "https://doi.org/10.1007/978-94-009-5261-4_5" @default.
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