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- W49642425 abstract "Photoabsorption in large mass-selected cluster ions is detected via evaporation of molecules from the cluster. The shape and size evolution of the absorption spectrum with cluster size provides a mechanism to identify the chromophore and to detect the extent of charge delocalization in the cluster ion. Photofragment mass spectra have been obtained for Br 2 − (CO 2 ) n ,I 2 − (CO 2 ) n and ICl − (CO 2 ) n cluster ions following photoexcitation of the 12 g ( 2 Π g,1/2 )←12 u ( 2 Σ u + ) transition in I 2 − and Br 2 − and the analogous transition in ICl - . Photodissociation of X 2 − within the cluster results in the production of both X - - and X 2 − -based ionic photofragments:" @default.
- W49642425 created "2016-06-24" @default.
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- W49642425 date "1994-01-01" @default.
- W49642425 modified "2023-10-16" @default.
- W49642425 title "Time Resolved Dynamics in Large Molecular Cluster Ions" @default.
- W49642425 doi "https://doi.org/10.1364/up.1994.thb.1" @default.
- W49642425 hasPublicationYear "1994" @default.
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