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- W49793087 abstract "Publisher Summary This chapter discusses the structural aspects of citrate biochemistry. The citrate ion is distributed throughout the human body and takes part in the all-important tricarboxylic acid (Krebs) cycle. The citrate ion is simple, just a backbone of five carbon atoms with carboxyl groups at C-1, C-3, and C-5 and an additional hydroxyl group on the central carbon atom, C-3. This backbone, studied in many crystal structures, can be fully extended, or one or both of the terminal carboxyl groups may be swung around, possibly forming a hydrogen bond to the central carboxyl group. For citrates studied in the crystalline state, it is found that the central carboxyl group and its adjacent hydroxyl group lie approximately in a plane perpendicular to the plane of the zigzag of the five-carbon backbone. One reason that the α-hydroxycarboxylate group is nearly planar may be its powerful chelating ability. Grenerally, this group with a bite of 2.56 A, binds metal ions. In the absence of a metal ion available to bind to this group, a hydrogen atom may bind in this place." @default.
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- W49793087 date "1992-01-01" @default.
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- W49793087 title "Structural Aspects of Citrate Biochemistry" @default.
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- W49793087 doi "https://doi.org/10.1016/b978-0-12-152833-1.50015-0" @default.
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