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• W4985364 abstract "The vapor phase clustering of water molecules (both homo-molecular and heteromolecular) influences atmospheric electro-optics, certain electrical phenomena, and helps remove pollutants through gas-to-particle conversion. The University of Missouri-Rolla Center for Cloud Physics Research has devoted a concerted effort toward developing the molecular description of clusters. In the microcrystalline approximation a given cluster structure is described by a factorized statistical mechanical partition function which contains the binding energy, translation and rotation factors, internal vibrations and rotations, and a contribution to the entropy. New quantum mechanical procedures continue to improve the knowledge of structural details and the frequencies and oscillator strengths of internal motions. Molecular dynamics investigations sharpen the understanding of conformational changes, collision dynamics, energy transfer, and growth and decay reactions. The experimental program has evolved information which along with other work has guided the development of theory. Careful homogeneous nucleation rate measurements delineate shortcomings in the classical liquid drop theory. Ion mobility measurements yield additional clues about the properties of equilibrium ion clusters. So far no theory is completely successful in describing clustering phenomena. Recent findings indicate that the less stable clusters may be more important than previously realized. A realistic evaluation of the theory will be given and possible avenues for future work discussed." @default.
• W4985364 created "2016-06-24" @default.
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• W4985364 date "1980-01-01" @default.
• W4985364 modified "2023-09-26" @default.
• W4985364 title "FUNDAMENTAL STUDIES ON VAPOR PHASE WATER CLUSTERS" @default.
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• W4985364 doi "https://doi.org/10.1016/b978-0-12-208440-9.50043-0" @default.
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