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- W49960520 abstract "This poster will describe a novel series of mol. scaffolds for the acceleration of iminium ion catalyzed processes. Drawing inspiration from Corey's 8-Ph menthol chiral auxiliary we have developed a concise synthesis of a new family of secondary amines and investigated their catalytic activity in the Diels-Alder reaction. Importantly, starting from (+)-pulegone as the source of chirality the nature of the asym. induction in the catalytic reaction can be altered by use of either the cis- or the trans-catalyst. Our investigations into variation of the nature of the arom. to modulate a proposed face-face π-π interaction in the transition state will also be reported. [on SciFinder(R)]" @default.
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- W49960520 date "2006-09-10" @default.
- W49960520 modified "2023-09-27" @default.
- W49960520 title "ORGN 140-8-Aryl menthamine-derived scaffolds for iminium ion catalysis" @default.
- W49960520 hasPublicationYear "2006" @default.
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