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- W50264835 abstract "Different industrial sectors are responsible for the generation of PVC-containing wastes that are currently disposed in landfill, which is an avoidable solution in terms of environmental policy and economical issues. Some of these wastes are an important potential source of energy and might be valorized using the gasification and pyrolysis processes. However, the presence of high chlorine contents in its composition prevents its management by a thermal process, as consequence of toxic compounds production and their release to the atmosphere. The present work asses a possible process for treating PVC materials/wastes in an environmentally friendly way. It is based on the effective de-chlorination of PVC containing materials/wastes through a pyrolysis process at low temperature before the material/wastes being submit to a subsequent thermal treatment for energetic valorization. DTA/TGA testing performed indicates that the temperature of 340 oC enables the removal of ~88 % of the chlorine present in the PVC material. The resulting polymeric fraction has also been characterized and it is mainly constituted by carbon. DTA/TGA testing up to 500oC shows that combustion reaction of the carbonaceous material is complete at 491oC demonstrating potential as a fuel source to a following gasification process in order to produce a synthesis gas with high energetic potential." @default.
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- W50264835 date "2012-01-01" @default.
- W50264835 modified "2023-09-24" @default.
- W50264835 title "Pyrolitic decomposition of PVC material and evaluation of the potential of the de-chlorination fraction for subsquent energy recovery process" @default.
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