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- W50720903 abstract "Bereits 1894 hat F. C. Phillips gefunden, dass in wässriger Lösung Palladium(II)-chlorid Ethen zu Acetaldehyd oxidiert (a). Das zweiwertige Palladium wird dabei zu metallischem Palladium reduziert. Es handelt sich also um eine stöchiometrische Reaktion: Acetaldehyd und Palladium werden in äquimolaren Mengen gebildet. Erst zwischen 1956 und 1959 ist in der Wacker-Chemie (Consortium für elektrochemische Industrie, München [Smi 1962]) eine katalytische Reaktionsführung gelungen, in der die Reoxidation des in stöchiometrischen Mengen gebildeten metallischen Palladiums mit Kupfer(II)-salzen durchgeführt wurde (b). Das dabei gebildete CuI wird dann mit Sauerstoff zu CuII oxidiert (c)." @default.
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- W50720903 date "2010-01-01" @default.
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- W50720903 title "Oxidation von Olefinen und Alkanen" @default.
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- W50720903 doi "https://doi.org/10.1007/978-3-8348-9375-8_13" @default.
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