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- W50843486 abstract "A new family of core/shell semiconductor based artificial photosynthetic systems that duplicate primary lightinduced charge separation mechanism in natural photosynthesis was created. This novel system is the important link for creating a new class of functional hybrid materials that weld the robustness and photoresponsiveness of inorganic materials (core) with the recognition properties of biological molecules (shell). This synthesis exploits our discovery that the surface of metal oxide nanocrystalline particles (TiO{sub 2}, Fe{sub 2}O{sub 3}, ZrO{sub 2},ZnO) differs from that of the respective bulk materials,and is characterized by a highly reactive undercoordinated surface. This can be viewed as a curse or as an opportunity. The coordination sphere of the surface metal atoms is incomplete resulting in their entacoordinated (square pyramidal) geometry. Due to the truncation of the crystal units at the surface and their weaker covalent bonding with solvent species compared to the bonding within the lattice, the energy level of the surface species are found in the mid-gap region thereby decreasing their reducing/oxidizing abilities. On the other hand, the incomplete surface exhibits high affinity for oxygen-containing ligands and gives the opportunity for chemical modification." @default.
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- W50843486 date "2006-01-01" @default.
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- W50843486 title "Toward electronically coupled bio-inorganic conjugates." @default.
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