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- W51134025 abstract "Publisher Summary The concept of gel-inhibitory agents that improve the solution processing parameters of the emeraldine base is introduced in the chapter. These agents are quite sensitive to the concentration range and the gel inhibitor/emeraldine base (GI/EB) molar ratio between 1 and 4. The preparation of highly concentrated EB solutions utilizing high molecular weight polyaniline is easily achieved with this processing advantage. The solutions are stable for periods of time sufficient to dry–wet spin fiber. The fiber moduli, strength, and DC conductivity are improved by stretch alignment. Mineral acids tend to weaken the fibers following doping protocols, while organic acids such as benzene phosphinic acid (BPA) preserve good mechanical and conductive properties. In the study described in the chapter, all of the doped samples showed temperature- dependant DC conductivity. This data can be fit to disorder models such as the quasi-one- dimensional variable-range hopping (VRH) model. Acetic acid is an anomalously poor dopant, and for polyaniline BPA is a good dopant." @default.
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- W51134025 date "1999-01-01" @default.
- W51134025 modified "2023-10-13" @default.
- W51134025 title "Electrically Conductive Polyaniline Fibers Prepared by Dry-Wet Spinning Techniques" @default.
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- W51134025 doi "https://doi.org/10.1016/b978-188420777-8.50020-5" @default.
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