Matches in SemOpenAlex for { <https://semopenalex.org/work/W51154222> ?p ?o ?g. }
Showing items 1 to 76 of
76
with 100 items per page.
- W51154222 endingPage "m256" @default.
- W51154222 startingPage "m253" @default.
- W51154222 abstract "The Cr4O4 hetero-cubane-centered octachromium(III) cluster [Cr8(PhCO2)16O4] crystallizes from fluorobenzene–acetonitrile as dodeca-μ2-benzoato-tetrabenzoatotetra-μ4-oxido-octachromium(III) acetonitrile tetrasolvate dihydrate, [Cr8(C7H5O2)16O4]·4C2H3N·2H2O, (I). Crystals produced by this method are significantly more stable than the originally published dichloromethane pentasolvate, [Cr8(PhCO2)16O4]·5CH2Cl2 [Atkinson et al. (1999). Chem. Commun. pp. 285–286], leading to a significantly higher quality structure and allowing the production of large quantities of high-quality nondeuterated and deuterated material suitable for inelastic neutron scattering (INS) measurements. Compound (I) reveals a higher symmetry structure in which the cluster sits on a twofold rotation axis, and is based on an asymmetric unit containing four crystallographically independent Cr positions, two oxide ligands, eight benzoate ligands, two acetonitrile solvent molecules and one disordered water molecule. All the Cr atoms are six-coordinate, with an octahedral geometry for the inner cubane and a more highly distorted coordination environment in the outer positions. Despite the higher symmetry, the coordination geometries observed in (I) are largely similar to the dichloromethane pentasolvate structure, indicating that crystal-packing effects have little influence on the molecular structure of [Cr8(PhCO2)16O4]. Close structural analysis reveals that the high magnetic anisotropy observed in the INS measurements is a consequence of the distorted coordination geometry of the four outer Cr atoms." @default.
- W51154222 created "2016-06-24" @default.
- W51154222 creator A5055368311 @default.
- W51154222 creator A5061184257 @default.
- W51154222 creator A5088650187 @default.
- W51154222 date "2010-08-20" @default.
- W51154222 modified "2023-09-26" @default.
- W51154222 title "[Cr<sub>8</sub>(PhCO<sub>2</sub>)<sub>16</sub>O<sub>4</sub>]·4CH<sub>3</sub>CN·2H<sub>2</sub>O: structural origin of magnetic anisotropy in a molecular spin cluster" @default.
- W51154222 cites W1641637347 @default.
- W51154222 cites W1828866216 @default.
- W51154222 cites W1985180244 @default.
- W51154222 cites W2031158103 @default.
- W51154222 cites W2032842297 @default.
- W51154222 cites W2071202770 @default.
- W51154222 cites W2080665513 @default.
- W51154222 cites W2086337833 @default.
- W51154222 cites W2093011705 @default.
- W51154222 cites W2098847775 @default.
- W51154222 cites W2118291488 @default.
- W51154222 cites W2122795000 @default.
- W51154222 cites W2131350133 @default.
- W51154222 doi "https://doi.org/10.1107/s0108270110032683" @default.
- W51154222 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20814097" @default.
- W51154222 hasPublicationYear "2010" @default.
- W51154222 type Work @default.
- W51154222 sameAs 51154222 @default.
- W51154222 citedByCount "2" @default.
- W51154222 countsByYear W511542222021 @default.
- W51154222 crossrefType "journal-article" @default.
- W51154222 hasAuthorship W51154222A5055368311 @default.
- W51154222 hasAuthorship W51154222A5061184257 @default.
- W51154222 hasAuthorship W51154222A5088650187 @default.
- W51154222 hasConcept C115624301 @default.
- W51154222 hasConcept C164866538 @default.
- W51154222 hasConcept C185592680 @default.
- W51154222 hasConcept C199360897 @default.
- W51154222 hasConcept C2777463227 @default.
- W51154222 hasConcept C2780750454 @default.
- W51154222 hasConcept C2781285689 @default.
- W51154222 hasConcept C41008148 @default.
- W51154222 hasConcept C43617362 @default.
- W51154222 hasConcept C71240020 @default.
- W51154222 hasConcept C8010536 @default.
- W51154222 hasConceptScore W51154222C115624301 @default.
- W51154222 hasConceptScore W51154222C164866538 @default.
- W51154222 hasConceptScore W51154222C185592680 @default.
- W51154222 hasConceptScore W51154222C199360897 @default.
- W51154222 hasConceptScore W51154222C2777463227 @default.
- W51154222 hasConceptScore W51154222C2780750454 @default.
- W51154222 hasConceptScore W51154222C2781285689 @default.
- W51154222 hasConceptScore W51154222C41008148 @default.
- W51154222 hasConceptScore W51154222C43617362 @default.
- W51154222 hasConceptScore W51154222C71240020 @default.
- W51154222 hasConceptScore W51154222C8010536 @default.
- W51154222 hasIssue "9" @default.
- W51154222 hasLocation W511542221 @default.
- W51154222 hasLocation W511542222 @default.
- W51154222 hasOpenAccess W51154222 @default.
- W51154222 hasPrimaryLocation W511542221 @default.
- W51154222 hasRelatedWork W1006345049 @default.
- W51154222 hasRelatedWork W1966095963 @default.
- W51154222 hasRelatedWork W1975533112 @default.
- W51154222 hasRelatedWork W2037131997 @default.
- W51154222 hasRelatedWork W2045182164 @default.
- W51154222 hasRelatedWork W2093367222 @default.
- W51154222 hasRelatedWork W2321870236 @default.
- W51154222 hasRelatedWork W2354954508 @default.
- W51154222 hasRelatedWork W2921812662 @default.
- W51154222 hasRelatedWork W887437746 @default.
- W51154222 hasVolume "66" @default.
- W51154222 isParatext "false" @default.
- W51154222 isRetracted "false" @default.
- W51154222 magId "51154222" @default.
- W51154222 workType "article" @default.