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- W52376988 abstract "Tin-119 Mössbauer spectroscopy shows that all powdered tin(II) compounds give a small tin(IV) signal that has been attributed to the presence of a very thin layer of SnO2 on the surface of the particles, that passivates against further oxidation, and is undetectable by X-ray diffraction. In a new development of this work, efficient passivation against further oxidation of the M1-xSnxF2 (M = Ca and Pb) solid solution poor in tin was found to be as high as for phases rich in tin, even though the amount of tin is way too low to be able to produce full coating of the particles by a thin layer of SnO2. This observation required developing a new model to explain the sluggish oxidation of phases poor in tin, based on bonding type and strength." @default.
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- W52376988 date "2006-01-01" @default.
- W52376988 modified "2023-09-23" @default.
- W52376988 title "A Thin Passivating Tin(IV) Oxide Layer on Tin(II)-Containing Fluoride Particles, or not? The M1-xSnxF2 Solid Solutions" @default.
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- W52376988 doi "https://doi.org/10.1016/b978-044452224-5/50026-3" @default.
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