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- W524 abstract "The Cryo-Thermochromatographic Separator (CTS) was designed and constructed for rapid, continuous on-line separation and simultaneous detection of highly volatile compounds of short-lived α-decaying isotopes of osmium and hassium (Hs, Z=108). A flowing carrier gas containing the volatile species is passed through a channel formed by two facing rows of 32 α-particle detectors, cooled to form a temperature gradient extending from 247 K at the channel entrance down to 176 K at the exit. The volatile species adsorb onto the SiO2-coated detector surfaces at a characteristic deposition temperature and are identified by their observed α-decay energies. The CTS was tested on-line with OsO4 prepared from 169–173Os isotopes produced in 118,120Sn(56Fe, 3,4,5n) reactions. An adsorption enthalpy for OsO4 of −40.2±1.5 kJ/mol on SiO2 was deduced by comparing the measured deposition distribution with Monte Carlo simulations. This successful result demonstrates that such a system provides a viable means for the first chemical study of hassium—which is expected to be a homologue of osmium—by determining whether it forms a similarly volatile oxide." @default.
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- W524 date "2002-05-01" @default.
- W524 modified "2023-10-14" @default.
- W524 title "The Cryo-Thermochromatographic Separator (CTS):" @default.
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- W524 doi "https://doi.org/10.1016/s0168-9002(01)01990-8" @default.
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