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• W52657376 abstract "The principles of activity coefficient determination using emf measurements and Pitzer's equations are discussed on the example of the NaCl + Na2SO4 + H2O system. Mean ionic activity coefficients of NaCl were determined in the O-4 mol kg–1 molality and 5–45°C temperature range using emf data measured in potentiometric cells without liquid junction. It was shown that in investigating the non-ideal characteristics of the unsymmetrical NaCl + Na2SO. + H2O system the effect of higher order electrostatic terms in the Pitzer equation cannot be neglected. It may be concluded from our data that the temperature coefficients of the mixing parameters are not significant and in a number of practical cases they can be considered as parameters not changing with temperature. For the system studied the mixing parameter values θCl,SO4 = = 0.0488 and ϕNa,Cl,SO4 = - 0.0065 are recommended. Irrespective of the different behaviour of the cells with silver-silver chloride thermal electrolytic type electrode and chloride ion-selective electrode, the activity coefficients determined agree sufficiently well." @default.
• W52657376 created "2016-06-24" @default.
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• W52657376 date "1989-01-01" @default.
• W52657376 modified "2023-10-15" @default.
• W52657376 title "APPLICATION OF ION-SELECTIVE ELECTRODES FOR DETERMINING THE MEAN ACTIVITY COEFFICIENTS OF ELECTROLYTES (EXEMPLIFIED BY THE NaCl + Na2SO4+ H2O SYSTEM)" @default.
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• W52657376 doi "https://doi.org/10.1016/b978-0-08-037933-3.50043-0" @default.
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