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- W52667905 abstract "The C-24 configurations of (22 E)-25,28-dimethylstigmasta-5,22,28-trien-3p-ol (1) and 25,28-dimethylstigmasta-5,28-dien-3β-ol (2), isolated from the sponge Topsentia ophiraphidites in our previous work, were determined to be both S, through the synthesis of stereodefined (24 S)- and (24 R)-epimers of 1 and 2 and comparison of the 1 H and 13 C NMR spectroscopic data. In addition, the C-24 configurations of the marine sterols having the same structures as 1 and 2 and their derivatives were also assigned for the first time by NMR comparison." @default.
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- W52667905 date "2014-12-01" @default.
- W52667905 modified "2023-09-26" @default.
- W52667905 title "C-24 Stereochemistry of Marine Sterols: (22E)-25,28-Dimethyl-stigmasta-5,22,28-trien-3β-ol and 25,28-Dimethylstigmasta-5,28-dien-3β-ol" @default.
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- W52667905 doi "https://doi.org/10.1177/1934578x1400901209" @default.
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