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- W53362959 abstract "Semiconductor properties of passive films formed on the Fe-18Cr alloy in a borate buffer solution (pH=8.4) and a 0.1 M H 2 SO 4 solution were examined using photoelectrochemical response and electrochemical impedance spectroscopy. Typical an n-type semiconductor behaviour is observed by both photo current and impedance for the passive films formed in the borate buffer solution. However, a negative photocurrent was observed in the 0.1 M H 2 SO 4 solution. This indicates that the passive film formed in acid behaves as a p-type semiconductor. However, Mott-Schottky plot of the capacitance showed typical n-type semiconductor property. It is concluded that the passive films on the Fe-18Cr alloys formed in the borate buffer solution is composed of both n-type outer hydroxide and inner oxide layers. On the other hand, passive film on Fe-18Cr alloy in 0.1 M H 2 SO 4 solution consists of p-type oxide and n-type hydroxide layers with isotype heterojunction. The kinetics of passive film growth and the corrosion behavior are discussed in terms of the electronic structure of the passive film." @default.
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- W53362959 date "2006-01-01" @default.
- W53362959 modified "2023-09-25" @default.
- W53362959 title "Photoelectrochemical Response and Corrosion Property of Passive Films on Fe-18Cr Alloy" @default.
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- W53362959 doi "https://doi.org/10.1016/b978-044452224-5/50046-9" @default.
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