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- W54293853 abstract "In the first research part, two libraries of ligands have been synthesized in parallel and evaluated in olefin polymerization: bridged ligands for metallocenes and deprotonated carbonylamino fulvene ligands. This work led to the discovery of active systems in homogeneous and heterogeneous catalysis of polymerization. The second part is the development of new high-thoughput methods for heterogeneous catalysis of olefins polymerization. Sealed bags, where the supported catalysts are introduced and the polymer is formed, produce in parallel various polymers from several different catalytic systems. The multi-spot plates method allows a quick and simple evaluation of catalysts in gas-phase polymerization. Finally, the last part is the development of a new technique for viscosimetric analysis with optical tweezers applied to poly(sodium 4-styrene sulfonate) in water. Comparisons between rheology governed by empirical laws and microrheology have been conducted to validate this analysis method." @default.
- W54293853 created "2016-06-24" @default.
- W54293853 creator A5041675592 @default.
- W54293853 date "2010-10-12" @default.
- W54293853 modified "2023-10-14" @default.
- W54293853 title "Développement de méthodes de criblages et en parallèle pour catalyse hétérogène de polymérisation d'oléfines gazeuses" @default.
- W54293853 hasPublicationYear "2010" @default.
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