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- W55268560 abstract "The desirability of the synthesis of materials at low temperatures is becoming evident in many major technologies. The principal obstacle is the slow kinetics of both combination and re-ordering to, and within, crystalline arrangements of ions at these low temperatures. This paper reviews several different methods, used by his group over the last 40 years. Results very recently developed in the author's laboratory are described in some detail. The methods for accelerating reactions in oxide materials at temperatures in the range of 0°-500°C include:1.Utilizing precursors made via solution-sol-gel and, recently, epitaxy via nanocomposite gel routes.2.Using low melting “fluxes.”3.(a)Hydrothermal processes.(b)Hydrothermal process with superimposed electric fields.(c)Hydrothermal process with mechanical forces.4.Mechano-chemical effects including very high uniaxial pressure and shear.5.Acoustic wave stimulation (sonochemical).6.Using of ionizing and non-ionizing radiation.7.Hydrothermal process with microwave fields.The results will show that several of these methods can accelerate reactions of the most common oxides by 1-2 orders of magnitude, and will therefore be technologically significant. The basic science behind the processes is still primitive." @default.
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- W55268560 date "1994-01-01" @default.
- W55268560 modified "2023-09-27" @default.
- W55268560 title "Catalysis of low temperature synthesis of ceramics" @default.
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- W55268560 doi "https://doi.org/10.1016/b978-1-4832-8382-1.50157-9" @default.
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