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- W55414863 abstract "Abstract The isomerization of 1-butene was carried out in order to detect trace amounts of acidic and/or basic impurities which are supposed to localize on the surfaces of the titled superconducting oxides. In was found that the superconducting oxides containing almost only a high critical-temperature phase (Tc=110K) showed no catalytic activity, whereas precursor compounds of the high Tc phase showed considerable activities as well as the selectivity featured by the base-catalyzed reaction. On the basis of the catalytic properties and other data of XRD, SEM, and Tc-measurement, we have concluded that CaO as an impurity remains on the surface of imperfect Bi-based superconducting oxides." @default.
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- W55414863 date "1994-01-01" @default.
- W55414863 modified "2023-09-27" @default.
- W55414863 title "3.14 Surface Properties and Catalytic Activities of Superconducting Bi-Pb-Sr-Ca-Cu Oxides for 1-Butene Isomerization" @default.
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- W55414863 doi "https://doi.org/10.1016/s0167-2991(08)61840-6" @default.
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