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- W55510513 abstract "3-Methoxy-7α-phenyl-1,5-dimethyl-3-borabicyclo[3.3.1]nonane 5 in solution at room temperature exists in the double chair conformation, as shown by NMR studies. Increasing the temperature leads to an increase in the population of the chair–boat conformation. At decreased temperature hindered rotation around the BO bond is observed for 5. Dissolving 5 in deuteropyridine leads to the reversible formation of complex 6, which exists in the chair–boat conformation. The chair–boat conformation is also the most stable one for chelate compound 7 with a tetracoordinated boron atom." @default.
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- W55510513 date "1999-11-01" @default.
- W55510513 modified "2023-10-17" @default.
- W55510513 title "Conformational behavior of 3-borabicyclo[3.3.1]nonanes" @default.
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- W55510513 doi "https://doi.org/10.1016/s0022-328x(99)00462-3" @default.
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