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- W55714182 abstract "The far infrared spectra of poly-L-alanine, poly-γ-methyl-L-glutamate, poly-γ-benzyl-L-glutamate and lysozyme were measured in the region below 800 cm-1. For lysozyme, the amide V bands due to the extended form, the disordered form and the α-helical form are observed at about 690, 650 and 600 cm-1 respectively. Low-frequency bands possibly arising from the α-helical main chain were observed at 375 cm-1 for poly-L-alanine and at about 410 cm-1 for poly-α, L-glutamate esters (methyl or benzyl). The infrared active chain vibrations were treated for the poly-L-alanine chains in the right-handed α-form and in the extended ∈-form and the nature of the observed infrared bands were elucidated. The correlations between the amide V bands and the chain conformations of polypeptide chains were also analysed. The chain vibrations of the left-handed α-helical form were also treated for analysing the infrared spectra of poly-L-aspartate esters. The dependences upon the helical senses are discussed for the amide I, II and V bands of the α-helical form." @default.
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- W55714182 date "1967-01-01" @default.
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- W55714182 title "Far Infrared Spectra, Chain Vibrations and Conformations of Polypeptides" @default.
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- W55714182 doi "https://doi.org/10.1016/b978-1-4832-2843-3.50012-1" @default.
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