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- W55860875 abstract "Copyright (c) 1997 Elsevier Science S.A. All rights reserved. The absorption spectrum of (e 8 -COT)Nd[HB(3,5-Me 2 pz) 3 (COT=cyclooctatetraenyl, pz=pyrazol-1-yl) has been measured at room temperature, at approximately 90 K and in parts at ca. 30 K. The bands were assigned by applying the selection rules for C 8v symmetry and by performing crystal field (CF) calculations assuming the CF parameters of the Nd complex were the same as for the previously analyzed (COT)Pr[HB(3,5-Me 2 pz) 3 . The parameters of an empirical Hamiltonian were fitted to the energies of 27 levels to give an r.m.s. deviation of 25.5 cm −1 . Neglecting the influence of [HB(3,5-Me 2 pz) 3 ligand, the CF strength of the [COT −− ligand could be estimated from the CF parameters obtained." @default.
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- W55860875 date "1997-03-01" @default.
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- W55860875 title "The electronic structure of organometallic complexes of the f elements XLI" @default.
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- W55860875 doi "https://doi.org/10.1016/s0925-8388(96)02553-4" @default.
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