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- W562529923 abstract "Polymer, namely poly(4-vinylpyridyne) (PVP) was used as a support for palladium catalysts acting in liquid phase of 2-ethylanthraquinone (eAQ), a key step in industrial production of hydrogen peroxide. The catalytic was carried out in a slurry reactor at atmospheric pressure of H 2 and temperature 43 °C. The progress of eAQ over Pd/PVP catalyst was the same as observed earlier in the presence of Pd/SiO 2 . In initial stage of reaction eAQ was reduced with high selectivity to eAQH2 (2-ethylanthrahydroquinone). In the further process termed deep hydrogenation of aromatic rings (formation of tetrahydroanthrahydroquinone H 4 eAQH 2 ) and hydrogenolysis of carbon-oxygen bonds (formation of products) in eAQH2 proceeded. It was stated that in the presence of mass transport limitations the progress of reactions leading to the formation of degradation products was intensive." @default.
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- W562529923 date "2002-01-01" @default.
- W562529923 modified "2023-09-24" @default.
- W562529923 title "Hydrogenation of 2-ethylanthraquinone over pd/poly(4-vinylpyridyne) catalysts" @default.
- W562529923 hasPublicationYear "2002" @default.
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