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- W563519991 abstract "1 The Basic Principles.- 1.1 Introduction.- 1.2 The Method.- 1.2.1 Metal Atom Source.- 1.2.2 The Reaction Site.- 1.2.3 Source of Coreactants.- 1.3 The Scope of the Technique.- 1.3.1 Synthesis of New Compounds.- 1.3.2 Improved Syntheses of Known Materials.- 1.3.3 A Quick Convenient Research Tool.- 2 Practical Aspects of Metal Vapour Synthesis.- 2.1 General Considerations.- 2.2 Pumping Systems.- 2.3 Vacuum Vessels.- 2.3.1 Static Vessels.- 2.3.2 Rotating Vessels.- 2.4 Reactant Inlet Systems.- 2.5 Vacuum Sealed Inlets for Electrical Supply.- 2.5.1 Low Tension.- 2.5.2 High Tension.- 2.6 Pressure Measurement.- 2.7 Vaporisation Sources.- 2.7.1 Resistance Heating.- 2.7.2 Electron Beam Heating.- 2.7.3 Laser Heating.- 2.7.4 Inductive Heating.- 2.7.5 Cathode Sputtering.- 2.7.6 Reactive and Activated Reactive Vaporisation.- 2.7.7 Ionised Cluster Beam Deposition.- 2.7.8 Electric Arc Heating.- 2.8 Vaporisation Sources for Matrix Isolation Spectroscopy.- 2.8.1 Foils and Wires.- 2.8.2 Knudsen Cells.- 2.8.3 Hollow-Cathode Sputtering Device.- 2.9 Leak Detection.- 2.10 General Experimental Procedures.- 2.10.1 Experiments with a Solid Matrix.- 2.10.2 Experiments in the Liquid Phase.- 2.10.3 Experiments in the Solid Phase.- 2.10.4 Experiments with Metal Slurries.- 2.10.5 Metal Aggregation and Catalysis.- 2.10.6 Cleaning.- 3 Properties of Metal Atoms and Interactions with Atoms and Molecules in Condensed Phases.- 3.1 Introduction.- 3.2 Metal Atoms in Matrices.- 3.2.1 Absorbtion Frequency Shifts in Matrix Isolated Metal Atom Spectra.- 3.2.2 Site Symmetry Effects.- 3.2.3 Reactions of Metal Atoms with Substrates.- 3.3 Metal-Metal Interactions: Aggregation.- 3.3.1 General Considerations.- 3.3.2 Dynamics of Metal Atom Aggregation.- 3.3.3 The Spectroscopic Characterisation of Metal Clusters.- 3.3.4 Nucleation and Free Energy of Small Clusters.- 3.3.5 Theoretical Considerations.- 3.4 Metal Atom Interactions in Synthetic Experiments.- 3.4.1 Vapour Zone.- 3.4.2 Cocondensation Zone.- 3.4.3 Rigid Matrix Zone or Period.- 3.4.4 Fluid Matrix Period.- 3.4.5 Solution Period.- 4 The Reactions of Metal Atoms.- 4.1 Types of Reaction.- 4.2 Carbon Monoxide.- 4.3 Carbon Monosulfide.- 4.4 Carbon Dioxide, Carbon Oxysulfide and Carbon Disulfide.- 4.5 Dinitrogen.- 4.6 Nitrogen Oxides.- 4.7 Phosphines and Phosphites.- 4.8 Isocyanides.- 4.9 Alkynes.- 4.10 Alkenes.- 4.11 Allyl.- 4.12 Alkadienes.- 4.12.1 Butadiene.- 4.12.2 Alkadienes with Active Hydrogens.- 4.12.3 Norbornadiene.- 4.13 Alkatrienes.- 4.13.1 Arenes.- 4.13.2 Cyeloheptatriene.- 4.14 Styrene.- 4.15 Alkatetraenes.- 4.16 Heterocycles.- 4.17 Boranes and Carboranes.- 4.18 Organic Halides.- 4.18.1 Reactions with Main Group Metal Atoms.- 4.18.2 Reactions with Transition Metal Atoms.- 4.19 Grignard Reagents.- 4.20 Inorganic Halides.- 4.21 Acids.- 4.22 Dioxygen.- 4.23 Dihalogens.- 4.24 Oxygen-Containing Organic Compounds.- 4.25 Sulfur-Containing Organic Compounds.- References.- Latest Developments in Metal Vapour Synthesis." @default.
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- W563519991 date "1979-01-01" @default.
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- W563519991 title "Metal vapour synthesis in organometallic chemistry" @default.
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