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- W565235067 abstract "Two silver(Ⅰ) complexes were obtained by the reaction of a N6 ligand with [Ag(PPh3)2(MeCN)](SbF6). In complex [AgL^1(PPh3)](SbF6) 1, the silver center is bound to three N donors of the nitrogen ligand and P donor of one triphenylphosphine group, forming an irregular AgN3P tetrahedron. In complex [Ag(PPh3)4](SbF6) 2, the Ag^+ ion is coordinated to four triphenylphosphine groups, affording a tetrahedral geometry. Crystal data for complex 1: C30H37AgF6N6PSb,Mr = 856.25, orthorhombic, space group Pbca, α = 19.0702(9), b = 15.9047(7), c = 21.498(1) A, V=6520.5(6) A^3, Z = 8, Dc = 1.744 g/cm^3, F(000) = 3408,μ = 1.544 mm^-1, the final R = 0.0367 and wR=0.1077 for 5325 observed reflections with I > 2σ(I); and those for 2: C72H60AgF6P4Sb, Mr =1392.70, trigonal, space group R3^-, α = 14.4577(6), b = 14.4577(6), c = 51.544(2) A, V= 9330.5(7)A^3, Z = 6, Dc= 1.487 g/cm^3, F(000) = 4224,μ = 0.913 mm^-1, the final R = 0.0352 and wR = 0.1089 for 3498 observed reflections with I >2σ(I)." @default.
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- W565235067 date "2004-01-01" @default.
- W565235067 modified "2023-09-24" @default.
- W565235067 title "Syntheses and Crystal Structures of Two Silver(I) Complexes Isolated by the Reaction of [Ag(PPh3)2(MeCN)](SbF6) with a N6 Ligand" @default.
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