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- W566651190 abstract "Composition of the mullite like compound (often called as X-phase in Si-Al-O-N system) were studied by the following experiments.(1) Correspondence between the composition of raw mixture and formed compound after hot-pressing the mixture at 1700°-1820°C.(2) Analytical results of the X-phase with E. P. M. A. and wet chemical analysis.(3) Correspondence between X-ray diffraction data collected with a “single” crystal of the X-phase and the analytical results.From the results of those experiments, it was concluded that the X-phase has very close composition to that proposed by L. J. Gauckler et al., Si4Al4O11N2. The atomic ratio, Al/Si was considered to be variable in a range, 1.0-1.8, but the ratio N/O was considered to be in fairly narrow range, 0.17-0.18 at about 1700°C. Typical compositional formula, Si6Al7O18N3 was proposed for the X-phase under fully occupied state." @default.
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- W566651190 date "1979-01-01" @default.
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- W566651190 title "The composition of mullite like compound appeared in Si-Al-O-N system." @default.
- W566651190 doi "https://doi.org/10.2109/jcersj1950.87.1007_371" @default.
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