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- W56970315 abstract "Transition metal atoms in their ground electronic state, when allowed to interact either with themselves or with other ligands in the solid or liquid phase, have proven to be valuable precursors to an extensive range of novel materials, which include ligand-free metal clusters, chemisorption models, organometal polymers, polymer protected metal colloids and supported metal cluster catalysts (Ref. 1).It is only very recently that attention has been directed to the chemistry of metal atomic reagents in selected excited electronic states and the majority of research so far has been restricted to microscale synthesis, utilizing matrix spectroscopic methods for detection and characterization of reactants and products. This kind of “Metal Atom Photochemistry” has been conducted in both weakly interacting and reactive low temperature solid supports and a number of hithertofore unobserved reaction pathways have recently been discovered for excited state transition metal atomic reagents which have not so far proven to be accessible to the respective ground state. These include, metal atom photonucleation processes, insertion into the CH bonds of saturated hydrocarbons, activation of dioxygen and oxidative-addition to dihydrogen.Experimental strategies, as well as, orbital, mechanistic and energetic considerations, which are currently thought to be important in evaluating the synthetic potential and reactivity patterns of electronically excited metal atomic reagents will constitute the essence of this paper." @default.
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- W56970315 date "1984-01-01" @default.
- W56970315 modified "2023-09-27" @default.
- W56970315 title "METAL ATOM PHOTOCHEMISTRY; ALKANE ACTIVATION USING EXCITED STATE METAL ATOMIC REAGENTS" @default.
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- W56970315 doi "https://doi.org/10.1016/b978-0-08-029249-6.50015-5" @default.
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