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- W57092380 abstract "The tellurium/molybdenum mixed oxides ((TeMo)O) catalyst system was investigated as part of the development of an industrial cerium/tellurium/molybdenum mixed oxides catalyst for propylene ammoxidation Catalysts containing 25% active phase on silica were prepared, characterized by BET surface area measurement, mercury porosimetry, X-ray diffraction, and optical microscopy, and tested for the ammoxidation of propylene at 400/sup 0/-460/sup 0/C in a flow reactor. The results suggested that Te/sub 2/MoO/sub 7/ is the active phase. The mechanism probably involves activation of propylene on a tellurium site and oxygen insertion at isolated and highly distorted MoO/sub 6/ octahedral sites. The addition of cerium to the binary catalyst prevents the reductive degradation of (TeMo)O which occurs under reactor flow conditions by a phase-separation process." @default.
- W57092380 created "2016-06-24" @default.
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- W57092380 date "1980-08-01" @default.
- W57092380 modified "2023-09-23" @default.
- W57092380 title "Structure and activity of tellurium/molybdenum oxide acrylonitrile catalysts. [Ammoxidation]" @default.
- W57092380 hasPublicationYear "1980" @default.
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