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- W571984040 abstract "Abstract β-nucleated impact-resistant propylene–ethylene copolymer (IPC) samples were prepared via melt compounding. The isothermal and non-isothermal crystallization and melting behaviors of the samples were investigated by means of differential scanning calorimetry (DSC). Avrami equation was used to analyze the isothermal crystallization kinetics of the samples. The Lauritzen–Hoffman theory was applied and the nucleation constant K g and the surface free energy σ e was calculated. Jeziorny’s and Mo’s methods were used to analyze the non-isothermal crystallization kinetics of the samples. The activation energy (Δ E ) of non-isothermal crystallization and the nucleating activity of the samples were calculated by Friedman’s formula and Dobreva’s method, respectively. The results show that the addition of β-nucleating agent (NT-A and NT-C) decreases the K g and σ e , so that the nucleation and crystallization rate of IPC is increased greatly under isothermal condition. Jeziorny’s and Mo’s methods well describe the non-isothermal crystallization kinetics of the samples. NT-C is more effective than NT-A as a β-nucleating agent. It is also found that the addition of nucleating agent decreases the size and increases the number of spherulites significantly. The Izod notched impact strength and heat deflection temperatures (HDT) of IPC are also improved by the nucleating agents." @default.
- W571984040 created "2016-06-24" @default.
- W571984040 creator A5001064541 @default.
- W571984040 creator A5086805985 @default.
- W571984040 date "2015-08-01" @default.
- W571984040 modified "2023-10-16" @default.
- W571984040 title "Crystallization kinetics, spherulitic morphology, mechanical properties and heat resistance of β-nucleated impact-resistant propylene-ethylene copolymer" @default.
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- W571984040 doi "https://doi.org/10.1016/j.tca.2015.06.011" @default.
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