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- W577179138 abstract "An overview is presented on recent developments in the use of hyphenated multidimensional separation and detection techniques for the characterization of polymeric materials. Emphasis has been placed on the use of on-line molecular-weight-sensitive detectors for size-exclusion chromatography (SEC). These detection systems are based on measuring Rayleigh light-scattering or intrinsic viscosity of the eluting polymer. With these types of detectors, one can determine absolute molecular weights as well as branching, molecular size, and polymer conformation as a function of molecular weight, without the use of column calibration. The determination of compositional heterogeneity using SEC with on-line selective detectors, such as UV, Fourier transform infrared, mass spectrometry, NMR, and even Raman spectrometry, is now being investigated. Multidimensional hyphenated techniques, such as orthogonal chromatography, temperature-rising elution fractionation—SEC, and SEC—high-performance liquid chromatography, are briefly discussed." @default.
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- W577179138 date "1995-05-05" @default.
- W577179138 modified "2023-09-27" @default.
- W577179138 title "Chromatographic Characterization of Polymers" @default.
- W577179138 doi "https://doi.org/10.1021/ba-1995-0247" @default.
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