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- W57962316 abstract "A method is described for determining the oxidation potentials for valency transitions in transplutonium elements (TPE), which is usable when the element is present in trace amounts. This is based on electrochemical oxidation or reduction of the TPE in combination with a solvent-extraction method of determining the concentration ratio for the oxidized and reduced forms. The method is applicable to determining the potential of almost any reversible reaction if the solvent-extraction parameters for the oxidized and reduced forms differ substantially, while the potential (with allowance for the extraction system) lies in a region accessible to electrochemical oxidation or reduction. Two forms of use are considered: with liquid extraction and with extraction chromatography. The method is demonstrated on the Bk(IV)/Bk(III) transition with di-2-ethylhexylphosphoric acid as extraction agent." @default.
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- W57962316 date "1987-03-01" @default.
- W57962316 modified "2023-09-26" @default.
- W57962316 title "Extraction radiopolarography for determining the oxidation potentials of transplutonium elements" @default.
- W57962316 hasPublicationYear "1987" @default.
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