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- W58093218 abstract "The effect of carbonaceous depositions on catalysts for hydrogenation reactions has been studied using hydrogenation of 2-ethylhexenal (A) to 2-ethylhexanal (B) and 2-ethylhexanol (C) on Ni/SiO2 as a model reaction. Starting with a fresh catalyst the activity decreased while the selectivity for producing B increased with time on stream. A catalyst pretreated with carbon monoxide or cyclopentadiene showed a lower activity but a higher selectivity than the fresh catalyst. Analysis of adsorbed hydrocarbons on the used catalyst, using temperature programmed desorption and extracting the hydrocarbons on the used catalyst in methylene chloride, showed large amounts of dimers." @default.
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- W58093218 date "1991-01-01" @default.
- W58093218 modified "2023-10-07" @default.
- W58093218 title "The Effect of Carbonaceous Depositions on Activity and Selectivity in Hydrogenation of an Unsaturated Aldehyde" @default.
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- W58093218 doi "https://doi.org/10.1016/s0167-2991(08)62629-4" @default.
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