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- W58123773 abstract "In the structure of the title compound, [Rb(4)(C(9)H(6)NO(4))(4)(H(2)O)(6)](n), the asymmetric unit comprises four rubidium cations, two of which have an RbO(7) coordination polyhedron with a monocapped distorted octa-hedral stereochemistry and two of which have a distorted RbO(6) octa-hedral coordination. The bonding about both the seven-coordinate cations is similar, comprising one monodentate water mol-ecule together with three bridging water mol-ecules and three carboxyl-ate O-atom donors, two of which are bridging. The environments around the six-coordinate cations are also similar, comprising a monodentate nitro O-atom donor, a bridging water mol-ecule and four bridging carboxyl-ate O-atom donors [overall Rb-O range = 2.849 (2)-3.190 (2) Å]. The coordination leads to a two-dimensional polymeric structure extending parallel to (001), which is stabilized by inter-layer water O-H⋯O hydrogen-bonding associations to water, carboxyl and nitro O-atom acceptors, together with weak inter-ring π-π inter-actions [minimum ring centroid-centroid separation = 3.5319 (19) Å]." @default.
- W58123773 created "2016-06-24" @default.
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- W58123773 date "2011-10-29" @default.
- W58123773 modified "2023-09-27" @default.
- W58123773 title "Poly[tetra-μ-aqua-diaquatetrakis[μ-(<i>E</i>)-2-nitrocinnamato]tetrarubidium]" @default.
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- W58123773 doi "https://doi.org/10.1107/s1600536811043406" @default.
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