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- W582655 abstract "HZSM-5 zeolite was completely deactivated during acetone conversion at 350°C as a result of the poisoning of bridging OH groups by the coke deposit as well as because of pore blocking. The coke residue was oxidized at 500°C to various degrees and the restoration of hydroxyl groups and void volumes was checked together with the changes in the remaining coke deposit. The most pronounced changes in the adsorption properties occurred when first coke layers were oxidized and the zeolite pores were opened. The catalytic properties were renewed with the reformation of bridging hydroxyls. During the oxidation, intermediates of ketonic, carboxylate and carbonate character were created, and decomposed yielding CO and CO2." @default.
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- W582655 date "1991-01-01" @default.
- W582655 modified "2023-09-27" @default.
- W582655 title "Coke Oxidation in Hzsm-5 Zeolites. Intermediates, Final Products and Reformation of oh Groups and Void Volumes" @default.
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- W582655 doi "https://doi.org/10.1016/s0167-2991(08)62925-0" @default.
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