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- W58514828 abstract "The uncertainties in calculated solubilities in the Na-F-PO{sub 4}-HPO{sub 4}-OH system. at 25 C for NaOH concentrations up to 5 mol/kg were assessed. These uncertainties were based on an evaluation of the range of values for the Gibbs energies of the solids. Comparative calculations using the Environmental Simulation Program (ESP) and SOLGASMIX indicated that the variation in activity coefficients with NaOH concentration is much greater in the ESP code than in SOLGASMIX. This resulted in ESP calculating a higher solubility in water and a lower solubility in NaOH concentrations above 1 mol/kg: There was a marked discrepancy in the solubilities of the pure components sodium fluoride and trisodium phosphate predicted by ESP and SOLGASMIX. In addition, different solubilities for these components were obtained using different options in ESP. Because of these observations, a Best Practices Guide for ESP will be assembled." @default.
- W58514828 created "2016-06-24" @default.
- W58514828 creator A5055586783 @default.
- W58514828 date "2000-07-25" @default.
- W58514828 modified "2023-09-23" @default.
- W58514828 title "Comparative Calculations of Solubility Equilibria" @default.
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- W58514828 doi "https://doi.org/10.2172/814615" @default.
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