FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W586218053> ?p ?o ?g. }

• W586218053 endingPage "16325" @default.
• W586218053 startingPage "16318" @default.
• W586218053 abstract "Numerous studies of the ionic conductivities in oxide-doped chalcogenaide glasses have shown the anomalous result that the ionic conductivity actually increases significantly (by more than a factor of 10 in some cases) by the initial addition of an oxide phase to a pure sulfide glass. After this initial sharp increase, the conductivity then monotonically decreases with further oxide addition. While this behavior is important to the application of these glasses for Li batteries, no definitive understanding of this behavior has been elucidated. To examine this effect further and more completely, the ionic conductivities of 0.5Li2S + 0.5[(1 − x)GeS2 + xGeO2] glasses have been measured on disc-type bulk glasses. The ionic conductivity of the 0.5Li2S + 0.5GeS2 (x = 0) glass was observed to increase from 4.3 × 10-5 (Ω cm)-1 to 1.5 × 10-4 (Ω cm)-1 while the activation energy decreased to 0.358 eV from 0.385 eV by the addition of 5 mol % of GeO2. Further addition of GeO2 monotonically decreased the conductivity and increased the activation energy. On the basis of our previous studies of the structure of this glass system, the Anderson and Stuart model was applied to explain the decrease in the activation energy and increase in the conductivity. It is suggested that the “doorway” radius between adjacent cation sites increases slightly (from ∼0.29(±0.05) Å to ∼0.40(±0.05) Å) with the addition of oxygen to the glass and is proposed to be the major cause in decreasing the activation energy and thereby increasing the conductivity. Further addition of oxides appears to contract the glass structure (and the doorway radius) leading to an increase in the conductivity activation energy and a decrease in the conductivity." @default.
• W586218053 created "2016-06-24" @default.
• W586218053 creator A5015751758 @default.
• W586218053 creator A5027804005 @default.
• W586218053 creator A5033070444 @default.
• W586218053 date "2006-07-29" @default.
• W586218053 modified "2023-10-18" @default.
• W586218053 title "Anomalous Ionic Conductivity Increase in Li₂S + GeS₂ + GeO₂ Glasses" @default.
• W586218053 cites W1963964945 @default.
• W586218053 cites W1972793502 @default.
• W586218053 cites W1975135493 @default.
• W586218053 cites W1975560764 @default.
• W586218053 cites W1986869214 @default.
• W586218053 cites W1995655908 @default.
• W586218053 cites W1996345036 @default.
• W586218053 cites W1998621708 @default.
• W586218053 cites W2000624541 @default.
• W586218053 cites W2004996046 @default.
• W586218053 cites W2009737499 @default.
• W586218053 cites W2019128676 @default.
• W586218053 cites W2029215657 @default.
• W586218053 cites W2031583906 @default.
• W586218053 cites W2035049672 @default.
• W586218053 cites W2036982050 @default.
• W586218053 cites W2039684400 @default.
• W586218053 cites W2043544274 @default.
• W586218053 cites W2047169065 @default.
• W586218053 cites W2055172824 @default.
• W586218053 cites W2057834325 @default.
• W586218053 cites W2068999267 @default.
• W586218053 cites W2078791849 @default.
• W586218053 cites W2086980567 @default.
• W586218053 cites W2088429357 @default.
• W586218053 cites W2325373134 @default.
• W586218053 cites W2356606775 @default.
• W586218053 cites W2897158599 @default.
• W586218053 doi "https://doi.org/10.1021/jp060670c" @default.
• W586218053 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16913758" @default.
• W586218053 hasPublicationYear "2006" @default.
• W586218053 type Work @default.
• W586218053 sameAs 586218053 @default.
• W586218053 citedByCount "73" @default.
• W586218053 countsByYear W5862180532012 @default.
• W586218053 countsByYear W5862180532013 @default.
• W586218053 countsByYear W5862180532014 @default.
• W586218053 countsByYear W5862180532015 @default.
• W586218053 countsByYear W5862180532016 @default.
• W586218053 countsByYear W5862180532017 @default.
• W586218053 countsByYear W5862180532018 @default.
• W586218053 countsByYear W5862180532019 @default.
• W586218053 countsByYear W5862180532020 @default.
• W586218053 countsByYear W5862180532021 @default.
• W586218053 countsByYear W5862180532022 @default.
• W586218053 countsByYear W5862180532023 @default.
• W586218053 crossrefType "journal-article" @default.
• W586218053 hasAuthorship W586218053A5015751758 @default.
• W586218053 hasAuthorship W586218053A5027804005 @default.
• W586218053 hasAuthorship W586218053A5033070444 @default.
• W586218053 hasConcept C113196181 @default.
• W586218053 hasConcept C131540310 @default.
• W586218053 hasConcept C138679309 @default.
• W586218053 hasConcept C145148216 @default.
• W586218053 hasConcept C147789679 @default.
• W586218053 hasConcept C17525397 @default.
• W586218053 hasConcept C178790620 @default.
• W586218053 hasConcept C185592680 @default.
• W586218053 hasConcept C191897082 @default.
• W586218053 hasConcept C192562407 @default.
• W586218053 hasConcept C2182769 @default.
• W586218053 hasConcept C2779851234 @default.
• W586218053 hasConcept C2780596425 @default.
• W586218053 hasConcept C43617362 @default.
• W586218053 hasConcept C44280652 @default.
• W586218053 hasConcept C49040817 @default.
• W586218053 hasConcept C540031477 @default.
• W586218053 hasConcept C54998646 @default.
• W586218053 hasConcept C57863236 @default.
• W586218053 hasConcept C68801617 @default.
• W586218053 hasConcept C95121573 @default.
• W586218053 hasConceptScore W586218053C113196181 @default.
• W586218053 hasConceptScore W586218053C131540310 @default.
• W586218053 hasConceptScore W586218053C138679309 @default.
• W586218053 hasConceptScore W586218053C145148216 @default.
• W586218053 hasConceptScore W586218053C147789679 @default.
• W586218053 hasConceptScore W586218053C17525397 @default.
• W586218053 hasConceptScore W586218053C178790620 @default.
• W586218053 hasConceptScore W586218053C185592680 @default.
• W586218053 hasConceptScore W586218053C191897082 @default.
• W586218053 hasConceptScore W586218053C192562407 @default.
• W586218053 hasConceptScore W586218053C2182769 @default.
• W586218053 hasConceptScore W586218053C2779851234 @default.
• W586218053 hasConceptScore W586218053C2780596425 @default.
• W586218053 hasConceptScore W586218053C43617362 @default.
• W586218053 hasConceptScore W586218053C44280652 @default.
• W586218053 hasConceptScore W586218053C49040817 @default.
• W586218053 hasConceptScore W586218053C540031477 @default.
• W586218053 hasConceptScore W586218053C54998646 @default.
• W586218053 hasConceptScore W586218053C57863236 @default.

• next