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- W586608518 abstract "During the reaction of di-2-pyridyl ketone (dpk) with Na(2)[PdCl(4)] in alcoholic media, the C=O fragment of dpk undergoes facile solvolysis and the transformed di-2-pyridyl ketone (dpk(ROH), R = Me or H) binds to palladium as NN-donor. When the reaction is carried out in refluxing methanol, a mono-complex of type [Pd(dpk(MeOH))Cl(2)] is obtained. A similar reaction in ethanol affords a bis-complex of type [Pd(dpk(ROH))(2)]Cl(2). Structure of both the complexes have been determined by X-ray crystallography. In acetonitrile solution the [pd(dpk(MeOH))Cl(2)] and [pd(dpk(ROH))(2)]Cl(2) complexes show intense absorptions in the visible and ultraviolet region, origin of which has been probed through uvr calculations. These two palladium complexes are found to be efficient catalysts for Suzuki cross-coupling reactions." @default.
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- W586608518 date "2011-08-31" @default.
- W586608518 modified "2023-09-24" @default.
- W586608518 title "Complexes of palladium using di-2-pyridyl ketone as ligand Synthesis, structure and, spectral and catalytic properties" @default.
- W586608518 doi "https://doi.org/10.5281/zenodo.5786108" @default.
- W586608518 hasPublicationYear "2011" @default.
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