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- W58705807 endingPage "768" @default.
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- W58705807 abstract "Abstract: This chapter provides a review of hydrogen interactions, gas phase hydrogen embrittlement (HE) and hydrogen environment embrittlement (HEE) in high purity aluminum and selected aluminum alloys. Hydrogen uptake occurs in Al alloys upon exposure to aqueous environments, water vapor saturated air and water vapor mixed with other gases such as nitrogen, argon or dihydrogen. Uptake does not readily occur in dry dihydrogen gas in the absence of water or water vapor. Uptake is favored when atomic hydrogen is produced either chemically (from a source such as dihydrogen, water dissociation, or other hydrogen containing molecules) or electrochemically (from water and proton reduction). The latter occurs spontaneously when water or protons are reduced on Al surfaces. This occurs more readily on transiently bare Al but is impeded by thick oxide films. Uptake and hydrogen accumulation may be limited by either water vapor transport to Al surfaces, surface reaction rates to produce atomic hydrogen from water, and diffusion through surface oxides and the metal. Solid state diffusion rates in aluminum when transport is dominated by perfect lattice rates of diffusion are typical of other face centered cubic materials such as nickel. However, hydrogen interacts with a variety of microstructural defects in Al and can become trapped at a variety of metallurgical sites. There are significant hydrogen-vacancy interactions and dissolved hydrogen may aid in vacancy formation. Embrittlement mechanisms remain controversial but hydriding, hydrogen induced local plasticity and hydrogen induced local decohesion are all possible mechanisms. These processes can degrade engineering significant parameters under both static and cyclic loading, such as fracture toughness, breaking stress and elongation to failure at a critical hydrogen level. Mitigation strategies can involve barrier-type coatings, ionic inhibitors to reduce corrosion and coupled hydrogen production as well as microstructural manipulation. The latter area is less well developed in the case of Al alloys given the difficulty of performing hydrogen analysis in this system. Future work should combine determination of engineering properties degraded by hydrogen with submicroscopic analysis of hydrogen metal interactions on Al alloys of commercial interest." @default.
- W58705807 created "2016-06-24" @default.
- W58705807 creator A5019962152 @default.
- W58705807 creator A5061312032 @default.
- W58705807 creator A5073061221 @default.
- W58705807 date "2012-01-01" @default.
- W58705807 modified "2023-09-26" @default.
- W58705807 title "Hydrogen embrittlement of aluminum and aluminum-based alloys" @default.
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