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- W58715466 abstract "Asymmetric benzoin and Stetter reactions exploit the catalytic reversal of aldehyde polarity to access 1,2- and 1,4-difunctionalized carbonyl derivatives. Enzymes, metallophosphites, and especially N -heterocyclic carbenes mediate the asymmetric benzoin and Stetter reactions with high levels of enantioinduction. This review discusses the advantages and limitations of these approaches in inter- and intramolecular benzoin and Stetter reactions, and it highlights the application of these reactions to cascade catalysis. Mechanistic discussions throughout the review aim to illuminate the proposed origin of selectivity in various transformations." @default.
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- W58715466 date "2012-01-01" @default.
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- W58715466 title "6.12 Benzoin and Stetter Reactions" @default.
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- W58715466 doi "https://doi.org/10.1016/b978-0-08-095167-6.00612-1" @default.
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